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991.
Influence of metallic properties on the fracture characteristics of Al2O3/Ti/Ni-laminated composites
Quan Liu Ke Xie Hongyan Xia Yifan Wu Weiguo Xu Minkun Jian Jianping Lin Mi Lu Guanjun Qiao 《International Journal of Applied Ceramic Technology》2022,19(6):3279-3287
The mutual confinement of ceramics and metals in laminated composites tends to change the original properties of ceramics and metals. In this study, two kinds of laminated composites, Al2O3/Ti and Al2O3/Ti/Ni, were prepared. Three-point bending experiments revealed that Al2O3/Ti underwent brittle fracture after elastic deformation. The fracture morphology analysis revealed that the Ti in Al2O3/Ti became brittle due to the formation of columnar crystals. The temperature gradient perpendicular to the direction of laminations during preparation was responsible for the formation of columnar crystals. The force–displacement curves of the Al2O3/Ti/Ni combine the properties of elastic deformation of ceramics and plastic deformation of metals. The reason why the Al2O3/Ti/Ni did not fracture completely in the bending experiments is that Ni maintained the toughness, and there is a good interfacial bond among Al2O3, Ti, and Ni. The indentation crack analysis revealed that cracks have long transverse propagation and short longitudinal propagation in both laminated composites. Finite element analysis revealed that this was due to compressive stress in the Al2O3 layer and tensile stress in the metal layer. This compressive stress consumes the crack energy in the longitudinal direction and stops the crack in the metal layer. The brittle to ductile gradient transition among Al2O3, Ti, and Ni, combined with the guidance of crack propagation direction by the interfacial layer, enhances the ability of Al2O3/Ti/Ni to resist damage. 相似文献
992.
Hongqiang Cui Yongze Cao Ying Li Lei Li Yuhang Zhang Guojian Li Yichao Wang Xiangping Li Baojiu Chen 《International Journal of Applied Ceramic Technology》2022,19(6):3358-3366
A series of Sr2.99-x(PO4)2:.01Er3+/xYb3+ (x = .02, .04, .06, .08, .10) phosphors in the presence of impurity Tm3+ were synthesized by high temperature solid-state method, and X-ray diffraction results show that these samples are pure R-3 m(166) space group phase. The upconversion luminescence (UCL) of Er3+ and impurity Tm3+ under 980-nm laser excitation were investigated, and the results show that the intense blue UCL of impurity Tm3+ and thermal enhancement of 2H11/2→4I15/2 of Er3+ simultaneously exist. When Er3+ doping concentration is kept at .01, both the blue UCL intensity of impurity Tm3+ and green and red UCL intensity of Er3+ reach the maximum at Yb3+ doping concentration of .08. The thermal enhancement effect of 2H11/2→4I15/2 of Er3+ was observed as high as 3.27 times from 303 to 723 K, which is because of lattice distortion and phonon-assisted transition. In addition, the optical temperature performance of Sr2.91(PO4)2:.01Er3+/.08Yb3+ sample was studied, and the maximum absolute temperature sensitivity was calculated as .00623 K−1 at 538 K. This study suggests that Sr3(PO4)2:Er3+/Yb3+ phosphors in the presence of impurity Tm3+ have a promising application prospect as optical temperature sensor at high temperature. 相似文献
993.
探究高温分解型澄清剂Na2SO4+C(炭粉)和氧化还原型澄清剂CeO2+NaNO3对超白浮法平板玻璃可见光透过率的影响。结果表明,随着Na2SO4和C量的增加,超白玻璃的可见光透过率随之增加,从91.30%提升至91.87%。而氧化还原型澄清剂中的CeO2质量分数小于0.07%时,超白玻璃的可见光透过率并没有实质性增加;CeO2质量分数超过0.07%时,增长趋势明显。相对于高温分解型澄清剂Na2SO4+C,氧化还原型澄清剂CeO2+NaNO3具有更显著的氧化性,有助于Fe2+/Fe总减少,但是Ce4+的自身着色和紫外截止效应影响了可见光透过率,建议使用量的质量分数不超过0.07%。 相似文献
994.
Dr. Lennart Brewitz Dr. Jos J. A. G. Kamps Dr. Petra Lukacik Claire Strain-Damerell Yilin Zhao Dr. Anthony Tumber Tika R. Malla Dr. Allen M. Orville Dr. Martin A. Walsh Prof. Dr. Christopher J. Schofield 《ChemMedChem》2022,17(9):e202200016
The two SARS-CoV-2 proteases, i. e. the main protease (Mpro) and the papain-like protease (PLpro), which hydrolyze the viral polypeptide chain giving functional non-structural proteins, are essential for viral replication and are medicinal chemistry targets. We report a high-throughput mass spectrometry (MS)-based assay which directly monitors PLpro catalysis in vitro. The assay was applied to investigate the effect of reported small-molecule PLpro inhibitors and selected Mpro inhibitors on PLpro catalysis. The results reveal that some, but not all, PLpro inhibitor potencies differ substantially from those obtained using fluorescence-based assays. Some substrate-competing Mpro inhibitors, notably PF-07321332 (nirmatrelvir) which is in clinical development, do not inhibit PLpro. Less selective Mpro inhibitors, e. g. auranofin, inhibit PLpro, highlighting the potential for dual PLpro/Mpro inhibition. MS-based PLpro assays, which are orthogonal to widely employed fluorescence-based assays, are of utility in validating inhibitor potencies, especially for inhibitors operating by non-covalent mechanisms. 相似文献
995.
996.
Zambaga Otgonbayar Kwang Youn Cho Chong-Hun Jung Won-Chun Oh 《Frontiers of Chemical Science and Engineering》2022,16(10):1438
The development of CO2 into hydrocarbon fuels has emerged as a green method that could help mitigate global warning. The novel structured photocatalyst is a promising material for use in a photocatalytic and magneto-electrochemical method that fosters the reduction of CO2 by suppressing the recombination of electron−hole pairs and effectively transferring the electrons to the surface for the chemical reaction of CO2 reduction. In our study, we have developed a novel-structured AgCuZnS2–graphene–TiO2 to analyze its catalytic activity toward the selective evolution of CO2. The selectivity of each nanocomposite substantially enhanced the activity of the AgCuZnS2–graphene–TiO2 ternary nanocomposite due to the successful interaction, and the selectivity of the final product was improved to a value 3 times higher than that of the pure AgCuZnS2 and 2 times higher than those of AgCuZnS2–graphene and AgCuZnS2–TiO2 under ultra-violet (UV)-light (λ = 254 nm) irradiation in the photocatalytic process. The electrochemical CO2 reduction test was also conducted to analyze the efficacy of the AgCuZnS2–graphene–TiO2 when used as a working electrode in laboratory electrochemical cells. The electrochemical process was conducted under different experimental conditions, such as various scan rates (mV·s–1), under UV-light and with a 0.07 T magnetic-core. The evolution of CO2 substantially improved under UV-light (λ = 254 nm) and with 0.07 T magnetic-core treatment; these improvements were attributed to the facts that the UV-light activated the electron-transfer pathway and the magnetic core controlled the pathway of electron-transmission/prevention to protect it from chaotic electron movement. Among all tested nanocomposites, AgCuZnS2–graphene–TiO2 absorbed the CO2 most strongly and showed the best ability to transfer the electron to reduce the CO2 to methanol. We believe that our newly-modeled ternary nanocomposite opens up new opportunities for the evolution of CO2 to methanol through an electrochemical and photocatalytic process. 相似文献
997.
Houjun Zhang Fang Chen Jipeng Xu Jinli Zhang You Han 《Frontiers of Chemical Science and Engineering》2022,16(6):886
Supercritical water gasification is a promising technology in dealing with the degradation of hazardous waste, such as oily sludge, accompanied by the production of fuel gases. To evaluate the mechanism of Fe2O3 catalyst and the migration pathways of heteroatoms and to investigate the systems during the process, reactive force field molecular dynamics simulations are adopted. In terms of the catalytic mechanisms of Fe2O3, the surface lattice oxygen is consumed by small carbon fragments to produce CO and CO2, improving the catalytic performance of the cluster due to more unsaturated coordination Fe sites exposed. Lattice oxygen combines with •H radicals to form water molecules, improving the catalytic performance. Furthermore, the pathway of asphaltene degradation was revealed at an atomic level, as well as products. Moreover, the adsorption of hydroxyl radical on the S atom caused breakage of the two C–S bonds in turn, forming •HSO intermediate, so that the organic S element was fixed into the inorganic liquid phase. The heteroatom O was removed under the effects of supercritical water. Heavy metal particles presented in the oily sludge, such as iron in association with Fe2O3 catalyst, helped accelerate the degradation of asphaltenes. 相似文献
998.
用溶胶凝胶法研究了Na2OB2O3SiO2KH560无机有机复合涂层胶凝过程,测定了溶胶的粘度,用DSC,TG,XRD,IR,SEM分析了凝胶的物相和结构,目测并在SEM下观察了这种胶凝材料涂覆在水泥砂浆表面后的表观性能,分析了影响这些性能的因素.在无机Na2OB2O3SiO2三组分系统中掺加有机改性剂KH560,无机相和有机相之间以化学键形式结合,形成无机有机互穿的杂化结构.经130°C低温处理即能制备出致密、不开裂,且具有良好物化特性的无机有机涂层材料.影响涂层性能的因素主要有KH560掺量、涂层液粘度、热处理制度(包括加热制度和冷却制度)等 相似文献
999.
以^13C核磁共振技术为主,红外光谱技术为辅,测定和分析了超临界CO2中合成的聚丙烯腈(简称CO2—PAN)的三单元组立构规整度,推测出其在三单元序列上符合Bernoulli理论统计模型。同时发现,用上述2种方法测定的结果一致性良好。 相似文献
1000.
Examining the carbon agenda via the 40% House scenario 总被引:2,自引:0,他引:2
《Building Research & Information》2007,35(4):363-378